Realizing that Charmander will not come with them, Ash and friends leave the Pokémon Center, and continue their search for Route 24. Not long after, they fall into a trap set on the road by Team Rocket, and Pikachu is captured.
When all hope seems lost, Charmander appears and saves Pikachu with its Flamethrower Move. As the charred Team Rocket runs away, Damian shows up having witnessed the impressive attack.
Team Rocket lays another trap on the road.
Season 1 - Episode 11
"Charmander -The Stray Pokémon"
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