Tired of running away and getting punched by the angry Pokémon, Ash has had enough and decides to fight back. The young trainer chooses Squirtle, but its water gun does little to weaken Primeape. Next, he sends Bulbasaur, whose Razor Leaf attack is also ineffective.
Finally, Ash releases Charmander, who struggles at first, but then uses Rage attack to increase its fire power beyond the normal levels and scorch its opponent. As Pikachu recovers Ash's hat, he catches Primeape with a Poké Ball.
Ash catches Primeape.
Season 1 - Episode 25
"Primeape Goes Bananas"
Primeape is defeated by Charmander.
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